His artistic approach relied on the precision of steel engraving. This method allowed for durable plates and fine lines. The process involved engraving into hardened steel, which allowed for thousands of impressions without loss of quality. Payne produced massive series titled Payne's Universum and the Royal Dresden Gallery, which contained views of cities and famous paintings. He supervised a large studio of engravers to ensure every plate met his standards for clarity. His work is defined by sharp detail and balanced compositions.

Modern collectors appreciate Payne for his accurate depictions of nineteenth-century Europe. His prints offer a window into urban scenes before the changes of the twentieth century. The neutral tones of his engravings suit various decor styles. These pieces provide a sense of history through their formal technique and architectural focus.